Tech Support Secrets
From http://support.wolfram.com/mathematica/kernel/Symbols/ you can access web pages Wolfram Research technical support provides for every built-in Mathematica symbol. In most cases you are linked to a web page that shows the usage message of the symbol and the full explanation from Appendix A.10 of the Mathematica Book for the selected symbol. The real value of this resource is the extra information provided for 30 or so kernel symbols. The extra information they provide about these symbols isn't available anywhere else! Unfortunately Wolfram Research does nothing to show which of the 1700+ symbols in the System context have this extra information.
I came across a lot of these pages with juicy bits of information and hyperlinks for the respective symbols are provided below.
AdjustmentBox
Apart
ArgumentCountQ
Assumptions
Coefficient
Compile
D
Derivative
Det
Dot
DSolve
Factor
FactorInteger
Flat
FullOptions
FullSimplify
HoldAllComplete
HoldComplete
Integrate
Interpolation
Interval
LinearProgramming
ListContourPlot
LUDecomposition
MakeRules
MatrixExp
MatrixQ
NDSolve
Notebook
OneIdentity
Permutations
Precision
Prime
PrimePi
Random
Residue
Return
Root
Roots
Series
Simplify
Solve
StoppingTest
Sum
Timing
Together
Union
Created by Mathematica (May 17, 2004)